4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate
نویسندگان
چکیده
The title compound, C15H13N3O3, exists in the E conformation with respect to the azo-methane C=N double bond. The pyridyl and phenyl rings form dihedral angles of 35.67 (8) and 36.65 (7)°, respectively with the central C(=O)N2C unit. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds connect the mol-ecules into chains along the b axis. Another C-H⋯O inter-action connects mol-ecules along the c-axis direction, forming layers.
منابع مشابه
Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate
The asymmetric unit of the title compound, C15H13N3O3·H2O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbon-yl)hydrazinyl-idene]meth-yl}phenyl acetate mol-ecule and a solvent water mol-ecule linked by O-H⋯O and O-H⋯N hydrogen bonds from the water mol-ecule and a C-H⋯O contact from the organic mol-ecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle be...
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متن کاملBis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ2 S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN 1)cadmium
The complete mol-ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa-hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S'-chelating dithio-carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine-aldazine (or 4-{[(pyridin-4-yl-methyl-idene)hyd...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013